teFazoe6207 teFazoe6207
  • 16-04-2018
  • Chemistry
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What reagent is needed to convert ch3ch2cooch2ch2ch3 to ch3ch2cho?

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transitionstate
transitionstate transitionstate
  • 25-04-2018
In this reaction ester is reduced to aldehyde. Such reduction can not be achieved by reacting reducing agents like LiAlH₄ because it will further reduce aldehydes to alcohols. So, in order to stop reduction at alddehyde, ester is reacted with bulky reducing agent, Diisobutylaluminium hydride (DIBAL) which works with same mechanism as that LiAlH₄ do. It also add hydride to carbonyl group. The reaction is shown below,
Ver imagen transitionstate
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